A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors.
نویسندگان
چکیده
We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid-base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 19 شماره
صفحات -
تاریخ انتشار 2015